Zirconium represents the ultimate corrosion-resistant material for lethal service pressure vessels handling the most aggressive chemical environments. This reactive metal forms a tenacious oxide film that resists attack by sulfuric acid at all concentrations up to boiling, hydrochloric acid to 37% concentration, and most organic acids. Zirconium maintains its protective oxide in conditions that breach the passive films on stainless steels and even nickel alloys, making it invaluable for containment of lethal substances in extremely corrosive environments.
When other materials fail in lethal service, zirconium often remains the only viable option. Concentrated sulfuric acid—a lethal substance requiring ASME lethal service designation—attacks stainless steels and many nickel alloys, but zirconium provides complete immunity. Hydrochloric acid at elevated temperatures and concentrations destroys most materials; zirconium handles these conditions safely. The material’s high cost is justified by its unmatched performance in applications where corrosion failure would release lethal substances, cause environmental catastrophe, or destroy critical production assets.
Zirconium for Highly Corrosive Applications lethal service vessels are used for:
• Hot concentrated sulfuric acid
• Hydrochloric acid processing
• Acetic acid production
• Formic acid handling
• Urea synthesis
• Phosphoric acid concentration
• Mixed acid environments
• Nuclear fuel reprocessing
• Complete sulfuric acid immunity (all conc.)
• HCl resistance to 37% concentration
• Organic acid resistance
• Operating temps: cryogenic to 550°F
• Low thermal neutron absorption
• Good mechanical properties
• Weldable with inert atmosphere
• Chemical Processing
• Pharmaceutical
• Nuclear
• Specialty Chemicals
• Fertilizer Production
All Roben lethal service pressure vessels are manufactured in accordance with:
• ASME Boiler and Pressure Vessel Code Section VIII, Division 1 and 2
• ASME B31.3 Process Piping Code
• EPA and OSHA regulations for highly hazardous chemicals
• DOT regulations for transportation of hazardous materials
• PED (Pressure Equipment Directive) for European compliance
Our quality management system ensures full material traceability, certified mill test reports, and documented fabrication procedures meeting the heightened requirements for lethal service equipment.
Under ASME Code, lethal service applies to vessels containing substances that are poisonous gases or liquids of such a nature that a very small amount mixed or unmixed with air is dangerous to life when inhaled. This classification triggers mandatory additional requirements including 100% radiographic examination of welds, post-weld heat treatment, and enhanced quality documentation. Roben Manufacturing maintains the expertise, certifications, and quality systems to meet these stringent requirements.
With over 65 years of pressure vessel fabrication experience, Roben Manufacturing has developed specialized capabilities for lethal service vessels in zirconium for highly corrosive applications. Our certified welders, qualified procedures, and rigorous quality systems ensure every vessel meets the heightened requirements for hazardous chemical containment. We work directly with customers to optimize material selection, design, and fabrication for safe, reliable, code-compliant lethal service equipment.
Lethal service designation under ASME Code triggers mandatory 100% radiographic examination of all butt welds, mandatory post-weld heat treatment (with limited exceptions), impact testing when applicable, and enhanced documentation requirements. Roben Manufacturing’s quality systems are designed to meet these requirements seamlessly.
We source materials exclusively from ASME-approved suppliers with certified mill test reports. Positive material identification (PMI) verifies alloy composition. Full material traceability from mill certificate through final installation ensures documentation integrity. Our material control procedures exceed standard requirements to provide the quality assurance essential for lethal service applications.
Absolutely. Our engineering team provides material selection guidance based on your specific process conditions, including temperature, pressure, chemical composition, and concentration. We consider both technical performance and economic factors to recommend optimal materials that meet safety requirements while controlling costs.
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Contact Roben Manufacturing to discuss your lethal service pressure vessel requirements.
Phone: (732) 364-6000
Email: sales@robenmfg.com
Address: 760 Vassar Avenue, Lakewood, NJ 08701